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Baeyer-Villiger oxidation Criegee intermediate

The Baeyer-Villiger oxidation is an oxygen insertion reaction whereby an aldehyde, cyclic or acyclic ketone 1 is treated with a suitable oxidant, e.g., an organic peracid 3, to form the corresponding formate, lactone or ester 2. The oxidation takes place in two discrete steps (1) the attack of the peroxide on the carbonyl to provide the Criegee intermediate, followed by (2) rearrangement to the product ester. [Pg.160]

A computational study of the Baeyer-Villiger oxidation of benzaldehyde and acetaldehyde has been reported. Computational studies with peroxyacetic acid suggest that the first step is rate limiting and the addition of the peroxyacetic acid oxidation catalyst to the ketone carbonyl to produce the Criegee or tetrahedral intermediate (Scheme 163) "... [Pg.524]

See other pages where Baeyer-Villiger oxidation Criegee intermediate is mentioned: [Pg.285]    [Pg.28]    [Pg.763]    [Pg.161]    [Pg.171]    [Pg.173]    [Pg.175]    [Pg.770]    [Pg.193]    [Pg.24]    [Pg.37]    [Pg.125]    [Pg.187]    [Pg.362]    [Pg.292]    [Pg.192]    [Pg.867]   
See also in sourсe #XX -- [ Pg.58 ]



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Baeyer Villiger

Baeyer Villiger oxidation

Baeyer oxidation

Criegee intermediates

Intermediate oxides

Oxidation intermediate

Oxidized intermediates

Villiger

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