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Azolyl complexes reactivity

The methyne proton of tris(pyrazolyl)methane is sufficiently acidic to be removed by raBuLi, and the resulting reactive intermediate readily reacts with electrophiles. Klaui prepared two new anionic tripodal nitrogen water-soluble ligands (the lithium salts of tris(pyrazolyl)- and tris(3-tert-butylpyrazol)-methanesulfonic, Tpms and Tmps B" respectively) by addition of lithiated tris(pyr-azolyl)methane to a sulfur trioxide-trimethylamine complex (Scheme 25).146... [Pg.200]

See other pages where Azolyl complexes reactivity is mentioned: [Pg.157]    [Pg.136]    [Pg.3]    [Pg.155]    [Pg.593]    [Pg.177]   
See also in sourсe #XX -- [ Pg.157 ]



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Azolyl complexes

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