Azines charge-transfer complexes

Dwivedi, P.C. (1970) Charge-transfer complexes of aromatic azines with iodine. Curr. ScL, 39, 107-109. 

The relaxation of the MLCT or charge-separated complex, for example, Re (COL/LL " )(L "+), where L and LL are, respectively, mono and bis azines, to the ground state can be regarded as an intramolecular electron transfer. The rate... 

In more elaborate studies, Kubiak and coworkers have established experimentally the existence of dynamic equilibrium mixtures containing charge-transfer isomers of mixed-valence ruthenium complexes within [ Ru3(p-0)-(p-CH3C00)6(12c1 0)(L ) ](p-BL)[ Ru3(p-0)(p-CH3C00)6( C 0)(L") ] by monitoring the v(CO) vibrations in the infrared (p-BL = unsymmetrical pyr-azine derivatives). The mixed-valence charge-transfer isomers differ in the... 

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