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Auto-oxidation mechanism

Scheme 1 Simplified auto-oxidation mechanism of polyolefins (PH is polymer substrate)... Scheme 1 Simplified auto-oxidation mechanism of polyolefins (PH is polymer substrate)...
Auto-Oxidation Mechanisms of Polymer Systems 7.6.1 ESR Spectrum ofPeroxy Radicals in Polymer Matrices... [Pg.349]

Bonchio, M., Carraro, M., Farinazzo, A., et al. (2007). Aerobic Oxidation of cis-Cyclooctene by Iron-Substituted Polyoxotungstates Evidence for a Metal Initiated Auto-Oxidation Mechanism, J. Mol. Catal. A Chem., 262, pp. 36-40. [Pg.622]

Scheme 6.1 General proposed auto-oxidation mechanism for polymers. R= polymer chain, H= most labile hydrogen, X = any radical, and k = reaction rate constant. Adapted from Ref [1]. Scheme 6.1 General proposed auto-oxidation mechanism for polymers. R= polymer chain, H= most labile hydrogen, X = any radical, and k = reaction rate constant. Adapted from Ref [1].
The earliest serious studies of polymer oxidation were by Bolland and his coworkers [8 to 11 ]. They proposed that this begins with a chain auto-oxidation mechanism. [Pg.132]

In another frequent case concerning aerobic oxidations, the role of the so-called catalyst is in reality the generation of carbon center radicals that by an auto-oxidation mechanism react with molecular oxygen forming peroxo radicals that abstract one hydrogen atom from another substrate molecule initiating a new chain (Scheme 2.9). Also in this case transition metals... [Pg.23]

See other pages where Auto-oxidation mechanism is mentioned: [Pg.652]    [Pg.166]    [Pg.459]    [Pg.243]    [Pg.536]    [Pg.349]    [Pg.351]    [Pg.353]    [Pg.355]    [Pg.357]    [Pg.359]    [Pg.782]    [Pg.77]    [Pg.446]    [Pg.501]    [Pg.960]   
See also in sourсe #XX -- [ Pg.349 , Pg.350 , Pg.351 , Pg.352 , Pg.353 , Pg.354 , Pg.355 , Pg.356 , Pg.357 , Pg.358 , Pg.359 ]



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