Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Auraptenol oxidative rearrangement

An oxidative rearrangement took place during the MCPBA epoxidation of the secondary allylic alcohol auraptenol, leading to the enal shown in equation (20). This reaction has been used in an approach to casegravol and in a synthesis of amottinin. The reason why the intermediate epoxy alcohol undergoes rearrangement in this case is not known beyond the possibility that the m-chlorobenzoic acid by-product could act as an acidic catalyst. [Pg.823]


See also in sourсe #XX -- [ Pg.823 ]

See also in sourсe #XX -- [ Pg.823 ]

See also in sourсe #XX -- [ Pg.823 ]




SEARCH



Oxidation oxidative rearrangement

Oxidation rearrangements

© 2024 chempedia.info