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AuCl catalyst, cycloisomerizations

Molecules containing allene and aUcene units that ate separated by several bonds are subject to cycloisomerization. With a catalyst derived from AuCl and a SEGPHOS ligand 16, chiral products of formal [2+2]cycloadditon are obtained. ... [Pg.138]

A computational study of the InCl3-, AuCl-, and PtCl2-catalysed cycloisomerizations of 2-(haloethynyl)biphenyl derivatives has shown catalyst-dependent selectivity 6-endo-dig cyclization favoured for InCl3- and AuCl-catalysedreactions (Scheme 113). " ... [Pg.508]


See other pages where AuCl catalyst, cycloisomerizations is mentioned: [Pg.485]    [Pg.150]    [Pg.501]    [Pg.502]    [Pg.475]    [Pg.477]    [Pg.58]    [Pg.255]   
See also in sourсe #XX -- [ Pg.508 ]




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AuCl catalyst

Cycloisomerism

Cycloisomerization

Cycloisomerizations

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