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ATRP atom transfer radical

The first reports of ATRP (Atom Transfer Radical Polymerization), which clearly displayed the characteristics of living polymerization, appeared in 1995 from the Laboratories of Sawamoto,2 Matyjaszewski266 and Percec.267 The literature on ATRP is now so vast that a comprehensive review cannot be... [Pg.486]

Recently, Kong et al. [159] functionalized MWNT with polyacrylic acid (PAA) and poly(sodium 4-styrenesulfonate) (PSS) by surface-initiating ATRP (atom transfer radical polymerization) following the Schemes 1 and 2 ... [Pg.513]

The last decades have witnessed the emergence of new living Vcontrolled polymerizations based on radical chemistry [81, 82]. Two main approaches have been investigated the first involves mediation of the free radical process by stable nitroxyl radicals, such as TEMPO while the second relies upon a Kharash-type reaction mediated by metal complexes such as copper(I) bromide ligated with 2,2 -bipyridine. In the latter case, the polymerization is initiated by alkyl halides or arenesulfonyl halides. Nitroxide-based initiators are efficient for styrene and styrene derivatives, while the metal-mediated polymerization system, the so called ATRP (Atom Transfer Radical Polymerization) seems the most robust since it can be successfully applied to the living Vcontrolled polymerization of styrenes, acrylates, methacrylates, acrylonitrile, and isobutene. Significantly, both TEMPO and metal-mediated polymerization systems allow molec-... [Pg.32]

Representative structm-e is Si/Si02//tethered block-6-outer block ATRP—atom transfer radical polymerization, RATRP—reverse atom transfer radical polymerization, RAFT—reversible addition fragmentation transfer polymerization... [Pg.131]

Development of ATRP (Atom Transfer Radical Polymerisation) by Wang, Matyjaszewski and Sawamoto... [Pg.43]

AFM=atomic force microscopy ATRP=atom transfer radical polymerisation PEO=poly(ethylene oxide)... [Pg.249]

ATRP atom-transfer radical polymerization bFGF basic fibroblast growth factor BSA bovine semm albumin... [Pg.2484]

See other pages where ATRP atom transfer radical is mentioned: [Pg.587]    [Pg.136]    [Pg.2]    [Pg.15]    [Pg.166]    [Pg.66]    [Pg.52]    [Pg.153]    [Pg.18]    [Pg.3]    [Pg.47]    [Pg.108]    [Pg.137]    [Pg.22]    [Pg.80]    [Pg.80]    [Pg.122]    [Pg.98]    [Pg.803]    [Pg.49]    [Pg.180]    [Pg.244]    [Pg.2]    [Pg.2]    [Pg.158]    [Pg.226]    [Pg.95]    [Pg.183]    [Pg.2]    [Pg.435]    [Pg.97]    [Pg.60]    [Pg.481]    [Pg.587]    [Pg.215]   


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Atom-transfer radical

Radical transfer

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