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Atomization enthalpies, computational procedures

A thermodynamic quantity of considerable importance in many combustion problems is the adiabatic flame temperature. If a given combustible mixture (a closed system) at a specified initial T and p is allowed to approach chemical equilibrium by means of an isobaric, adiabatic process, then the final temperature attained by the system is the adiabatic flame temperature T. Clearly depends on the pressure, the initial temperature and the initial composition of the system. The equations governing the process are p = constant (isobaric), H = constant (adiabatic, isobaric) and the atom-conservation equations combining these with the chemical-equilibrium equations (at p, T ) determines all final conditions (and therefore, in particular, Tj). Detailed procedures for solving the governing equations to obtain Tj> are described in [17], [19], [27], and [30], for example. Essentially, a value of Tf is assumed, the atom-conservation equations and equilibrium equations are solved as indicated at the end of Section A.3, the final enthalpy is computed and compared with the initial enthalpy, and the entire process is repeated for other values of until the initial and final enthalpies agree. [Pg.543]


See other pages where Atomization enthalpies, computational procedures is mentioned: [Pg.138]    [Pg.70]    [Pg.73]    [Pg.294]    [Pg.381]    [Pg.1364]    [Pg.320]    [Pg.395]    [Pg.193]    [Pg.395]    [Pg.793]    [Pg.809]    [Pg.7]    [Pg.131]    [Pg.436]   
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Atomization enthalpy

Computational procedures

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