Atomic resonance absorption bromine atom

Bromine-atom atomic resonance absorption spectrometry (ARAS) has been applied to measure the thermal decomposition rate constants of CF3Br in Kr over the temperature range 1222-1624 K. The results were found to be consistent with recently published theory. The formation of cyclopent[a]indene and acenaphthylene from alkyl esters of biphenyl-mono- and -di-carboxylic acids has been observed in flash vacuum pyrolyses at 1000-1100 °C. The kinetics and mechanisms of free-radical generation in the ternary system containing styrene epoxide, / -TsOH, and i-PrOH have been examined in both the presence and absence of O2. ... 

Spin-orbit populations in halogen atom products have also been measured by time-resolved resonance absorption spectroscopy in the vacuum ultraviolet [77,78], in much the same way as the collisional loss of reactant atoms has been monitored. Laser techniques are finding increasing use in the detection of atomic products. Bromine atom product populations in the 1/2 states have been... 

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