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Asymmetric synthesis of indolizidine alkaloids

The asymmetric synthesis of indolizidine alkaloids is described utilizing a palladium-catalyzed amination process. Ionization of an allylic carbonate provides a symmetrical rr-allyl palladium complex, subsequent reaction with a protected homoallylamine gave the product in 93% yield and >99.5% ee (eq 5). ... [Pg.101]


See also in sourсe #XX -- [ Pg.6 , Pg.442 , Pg.443 ]

See also in sourсe #XX -- [ Pg.6 , Pg.442 , Pg.443 ]




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Asymmetric synthesis alkaloids

Indolizidine

Indolizidine alkaloids asymmetric synthesis

Indolizidine alkaloids, synthesis

Indolizidines

Indolizidines, synthesis

Of -indolizidine

Of -indolizidine alkaloid

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