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Aryl halides bidentate diphosphine ligands

C.i. Rate and Mechanism of the Oxidative Addition of Aryl Halides to Palladium(O) Complexes Ligated by Bidentate Diphosphine Ligands... [Pg.966]

Vanadium, Niobium, and Tantalum.—Photochemical reactions of CpV(CO)4 with Group Vb donor ligands have given products of the types CpV(CO)3XRs (X = As, Sb, or Bi R = alkyl, Ph, OEt, etc.f and CpV(CO)2L (L = bidentate diphosphine, diarsine, or arsine-phosphine ligand). The dianion [CpV(C0)3] , prepared by reduction of CpV(CO)4 with Na in THF, has been converted into the isolable salt [(Ph3P)2N]+[CpV(CO)3H], which effects hydro-genolysis of various alkyl, aryl, and acyl halides apparently by a radical-chain mechanism. ... [Pg.373]

See other pages where Aryl halides bidentate diphosphine ligands is mentioned: [Pg.443]    [Pg.1287]    [Pg.158]    [Pg.535]    [Pg.1287]    [Pg.71]    [Pg.6]   
See also in sourсe #XX -- [ Pg.966 , Pg.968 ]



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Aryl ligands

Arylation ligand

Bidentate diphosphine

Bidentate ligands

Bidentates

Diphosphine

Diphosphine ligands

Diphosphines

Halide ligands

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