Artifacts geographical distribution

While some caution must still be used in interpreting how closely samples must match, it is clear that analysis of the REE in soapstone can be used to obtain new information about the utilization of lithic resources. The reasons that this group of elements can identify the source of soapstone are geochemical. Soapstone is a relatively rare lithic resource formed by fairly complex metamorphic processes which leave a "fingerprint in terms of the trace element content. The distribution of material with this "fingerprint will help archaeologists to imderstand the process and pattern patterns of resource procurement. However, the examples discussed above show that it is also important to know age of the artifacts to interpret the geographical distribution patterns. 

Geographical Distribution. It should prove very interesting to look at the possible gum sources for an artifact or artwork whose origins are documented. Local occurrence of the specific plant would be no surprise. If the gum is unavailable locally, three conclusions might be implied. First, the artist or school may have had a preference for this particular type of gum, which will be an aid in authenticating other pieces when... 

During the isolation of cathinone, 3,6-dimethyl-2,5-diphenyl pyrazine (3) was also found (14). This is doubtless an artifact, the product of oxidative dimerization of cathinone which involves the formation of condensation product 4 as an intermediate (18). Also found was the diketone (5) and the cinnamoyl compound (6) (14), later shown to have the (S) stereochemistry illustrated and named merucathinone (6,19,20). Merucathine (7) has also been isolated (6,21,22), and this and merucathinone are minor components. (-)-Norephedrine (8) also occurs in khat (14), and its iV-formyl derivative (9) has been found in plant material of South Arabian origin (23). Despite earlier positive reports, ephedrine and pseudoephedrine have not been verified as components of khat (14). HPLC has been employed to separate and quantify mixtures of the khatamines cathinone, (+)-norpseudoephedrine, and (—)-norephedrine in connection with a study of their distribution in different parts of the khat plant and in specimens of different geographical origin (20,21). 

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