Sulfur—arsenic bonds elemental halogens

The magnetic criterion is particularly valuable because it provides a basis for differentiating sharply between essentially ionic and essentially electron-pair bonds Experimental data have as yet been obtained for only a few of the interesting compounds, but these indicate that oxides and fluorides of most metals are ionic. Electron-pair bonds are formed by most of the transition elements with sulfur, selenium, tellurium, phosphorus, arsenic and antimony, as in the sulfide minerals (pyrite, molybdenite, skutterudite, etc.). The halogens other than fluorine form electron-pair bonds with metals of the palladium and platinum groups and sometimes, but not always, with iron-group metals. 

Several organoarsenic(III) compounds containing arsenic(III)-transition metal bonds have been oxidized by halogen-based electrophiles or by elemental sulfur to give the corresponding dihalides or sulfides (equations 365 , 366 and 367 - ). 

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