Architecture generation

Figure 1.10 Comparison of dendrimer and dendrigraft architecture Generation 0-2...

The variation of the size of the dendrimer with the number of segments, n, between two branch points, at constant architecture (generation), has been consid-... 

Chiral supramolecular architectures generated from non-chiral monomeric units were reported in a number of systems in solution and have been summarized in a comprehensive review [114]. An amplification of chirality on hydrogen-bonded assemblies, controlled by different substitutions and structural variations in the building blocks, has been recently described by Rein-houdt et al. [115]. 

Davis JT, Spada GP (2007) Supramolecular architectures generated by self-assembly of guanosine derivatives. Chem Soc Rev 36 296-313... 

Supramolecular architectures generated by self-assembly of guanosine derivatives 07CSR296. 

Scheme 6.4 PPE-containing architectures generated with the Mortreux Mo(CO)6/4-chlorophenol system.

Architectural exploration and behavioral partitioning. Micro-architecture generation. 

Macrocyclic systems with a discotic architecture generate mesophases. In the case of the alicyclic azacrown systems e.g., 25), the molecnles assemble in a colunmar fashion and due to the hollow nature of the molecules, the mesophase has been denoted as tubular. 

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