Aqueous and interfacial chemistry

NaCl (s) + H2SO4 NaHS04 + HCl (g) NaCl (5) + N2O5 NaNOj + NO2CI 

we present the following speculative scheme of multiphase chemical production of atomic Cl from dissolved HCl (its oxidation by H2O2 is described in Gmelin 1927)  

Assuming photocatalytic H2O2 formation in liquid films, the above scheme would represent another radical source via the aqueous phase without the consumption of gas phase-produced oxidants and a recycling between HCl and atomic Cl. This 

Only in the past few years has evidence been found that SSA also occurs in the very fine fraction below 250 nm (down to 10 nm) depending on the sea state (Nilsson et al. 2001, Geever et al. 2005, Clarke et al. 2006). In Chapter 2.4.3.3, we presented knowledge of HCl degassing from sea salt. Brimblecombe and Clegg (1988) described the equilibrium  

In aqueous solution, hypochlorous acid HOCl (and HOBr and HOI) is produced by CI2 hydrolysis 5.408 = 0.4 cm molecule s b 

---