Approaches to Organolead Compounds

Historically, the first metalloorganic method for the synthesis of organolead compounds was based on the use of zinc dialkyls. It was not surprising that the method was first 

In 1932, Austin680 used for the first time organolithium compounds for the synthesis of organoleads. He reported that the reaction of ArLi with PbCl2 led to A Pb. Further heating of the latter led to products such as A Pb, A PbPbA and pb680,1180,1181. 

The transformations of compounds Pt PbM (M = Li, Na) and their possible use for synthetic purposes started to develop in 1939, but the basic investigations in this field were carried out after 1960. 

Triphenylplumbyllithium was introduced into synthetic practice by Gilman and Summers239,1193 only in 1952. In 1952, D Ans and coworkers986 used Pl PbLi to obtain fluorenyllithium. In 1932, Shurov and Razuvaev1194 studied the transfer of phenyl radicals, formed by the thermolysis of Ph M (M = metal) to another metal atom, which formed 

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