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Applications to metal carbonyls with known heats of formation

3 Applications to metal carbonyls with known heats of formation [Pg.1077]

If the enthalpy of formation of a particular metal carbonyl cluster compound M.v(CO). has been measured, typically by calorimetric determination of the enthalpy of combustion, one can calculate the enthalpy of disruption of that cluster in [Pg.1077]

All data on structure, enthalpy of atomization (in kcal mol ) and metal-metal bond lengths were taken from CRC Handbook of Chemistry and Physics, ed. D. R. Lide, 72 edn, CRC Press, Boca Raton. [Pg.1078]

For the metals with bcc structure the metal-metal bond length quoted is the 8-coordinate distance for the fee and hep metals the distance quoted is the 12-coordinate distance. [Pg.1078]

For metals which have more than one phase the table indicates the phase for which data have been taken. [Pg.1078]




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Carbonylation with metal carbonyls

Formates, metalated

Formation, heat

Heat applications

Heat of formation

Heat of formation heats

Heat of metals

Known

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Metal applications

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Metals, formation

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