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Anti periplanar molecular model

Draw (IS,2S)-l,2-dibromo-l,2-diphenylethane so that you can see its stereochemistry and so that the -H and -Br groups to be eliminated are anti periplanar (molecular models are ex( remely lielpful here). Elimination of HBr from this conformation gives (Z)-l-bromo-l,2-diphenylethylene. [Pg.417]

Although anti periplanar geometry is preferred for E2 reactions, it isn t absolutely necessary. The deuterated bromo compound shown here reacts with strong base to yield an undeuterated alkene. Clearly, a svn elimination has occurred. Make a molecular model of the reactant, and explain the result. [Pg.405]

Molar absorptivity. 502 Molecular ion (M+), 410 Molecular mechanics. 130 Molecular model, dopamine, 930 acetaminophen, 29 acetylene, 18 adenine, 67 adrenaline, 323 alanine, 28, 1016 alanylserine, 1028 rr helix, 1039 p-aminobenzoic acid, 25 anti periplanar geometry, 387 a recoline, 79 aspartame, 29 aspirin. 17 ball-and-stick, 61 /3-pleated sheet, 1039 p-bromoacetophenone, 449 bromocyclohexane, 121 butane, 80... [Pg.1306]


See other pages where Anti periplanar molecular model is mentioned: [Pg.513]    [Pg.1286]    [Pg.81]    [Pg.46]   
See also in sourсe #XX -- [ Pg.482 ]




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