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Anomalies, Special Cases and Non-linearity

Free energy relationships are predominantly linear, even slightly curved plots are rare, and there are several cases where the free energy relationships are linear over very large ranges of rate constant. The existence of non-systematic scatter of data points (see Section 6.4) can make it difficult to demonstrate curvature (or its absence) even when the data points are for structurally similar reagents. [Pg.129]

Curvature is most reliably detected in proton transfer reactions [Pg.130]

When a rate constant for proton transfer within the encounter complex is larger than that of complex formation or decomposition i.e. k2 k x or k 2 k Equations (2) reduce to Equations (3)  [Pg.130]

See other pages where Anomalies, Special Cases and Non-linearity is mentioned: [Pg.129]    [Pg.131]    [Pg.133]    [Pg.135]    [Pg.137]    [Pg.139]    [Pg.141]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.129]    [Pg.131]    [Pg.133]    [Pg.135]    [Pg.137]    [Pg.139]    [Pg.141]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]   


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