Anodic oxidation of enecarbamates

Indeed, the anodic oxidation of enecarbamates in acetic acid in the presence of potassium or sodium acetate yields the corresponding a,/ -diacetoxycarbamates in reasonable yields (equation 10). 

When ammonium chloride is used as the supporting electrolyte in the anodic oxidation of enecarbamates in acetonitrile or methanol, chlorination at the -position takes place. In the mechanism of this -chlorination, the electron transfer from the unsaturated bond of the enecarbamate may not be involved, but the chloride ion is anodically oxidized to a positively charged active species which subsequently adds to the -position of the... 

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See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

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