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Angular group induced bond alternation - a new substituent effect detected by molecular geometry

Angular group induced bond alternation - a new substituent effect detected by molecular geometry [Pg.174]

Recently it has been found that the angular substituent, the methoxy group, induces an imbalance of the Kekule structures, based on the calculated (6-3IC ) geometry for anisole [66]. The observed imbalance is presented in Fig. 16. [Pg.174]




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A bonds substituents

A-Substituent effects

Alternative Groups

Angular geometries

Bond alternation

Bonding geometry

Bonds geometry

Effect inducing

Effect, alternation

Geometry, molecular

Groups substituents

Molecular bonding

New molecular

Substituent groups

Substituent groups bonds

Substituents angular

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