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Angular-dependent adiabatic potential energy

The angular-dependent adiabatic potential energy curves of these complexes obtained by averaging over the intermolecular distance coordinate at each orientation and the corresponding probability distributions for the bound intermolecular vibrational levels calculated by McCoy and co-workers provide valuable insights into the geometries of the complexes associated with the observed transitions. The He - - IC1(X, v" = 0) and He + 1C1(B, v = 3) adiabatic potentials are shown in Fig. 3 [39]. The abscissa represents the angle, 9,... [Pg.383]


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Adiabatic potential

Adiabatic potential energy

Energy-dependent

Potential dependence

Potentials angular-dependent

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