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An Alternative Derivation for Hard Rods

For hard particles interacting via a pair potential of the form (4.5.20), the canonical PF (4.5.6) simplifies considerably. Since Un is either zero or infinity, the integrand PUm) is 1, when the configuration X, . Xn is allowable and 0 otherwise. A configuration of the particles is allowable whenever no two particles come closer than the length cr of the rods. [Pg.231]

The first particle is allowed the region between g/I and X — cr, the second the region between the first and the third hard rods, etc. [Pg.231]

One can now perform the integration step by step. For instance, the first two steps are [Pg.231]

In the second step we changed variables, V2 = X2 — (3/2)a. Similarly at each step we change variables. [Pg.231]

In this way the integration (4.5.29) can be performed successively and the final result is [Pg.231]


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