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Amylose phenylcarbamates, chiral recognition

Enomoto, N., Furukawa, S., Ogasawara, Y., Akano, H., Kawamura, Y., Yashima, E., and Okamoto, Y. (1996) Preparation of silica gel-bonded amylose through enzyme-catalyzed polymerization and chiral recognition ability of its phenylcarbamate derivative in HPLC, Anal. Chem. 68, 2798-2804. [Pg.321]

Amylose has also been derivatized into various phenylcarbamates and evaluated as CSPs in HPLC [48,49]. Again, 3,5-dimethylphenylcarbamate (32, Fig. 15) is one of the most useful derivatives and has been commercialized as Chiralpak AD from Daicel. Chiral recognition of the amylose derivative is rather complimentary to that of 31x, and many compounds that are difficult to resolve on 31x can be resolved on the amylose derivative 32. With these two 3,5-methylphenylcarbamates, nearly 80% of 500 racemates have been resolved by my group [43]. [Pg.404]

Structural Analysis of Phenylcarbamate Derivatives of Cellulose and Amylose Chiral Recognition Mechanism. [Pg.33]


See other pages where Amylose phenylcarbamates, chiral recognition is mentioned: [Pg.173]    [Pg.173]    [Pg.178]    [Pg.179]    [Pg.184]    [Pg.51]    [Pg.54]    [Pg.56]    [Pg.308]    [Pg.310]    [Pg.658]    [Pg.1020]    [Pg.208]    [Pg.209]    [Pg.658]    [Pg.391]    [Pg.405]    [Pg.33]    [Pg.39]    [Pg.159]    [Pg.186]    [Pg.1371]    [Pg.1372]   
See also in sourсe #XX -- [ Pg.172 , Pg.173 , Pg.174 , Pg.175 , Pg.176 , Pg.177 , Pg.178 ]




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