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Amines oxygen atom transfer from hydroperoxides

VII. OXYGEN ATOM TRANSFER FROM SELECTED HYDROPEROXIDES A. The Oxidation of Amines... [Pg.67]

Cytochrome P-450 Catalyzed Reactions - Studies with 02 have established that the cytochrome P-450 mediated hydroxylation of camphor by the bacterial enzyme and the enzyme purified from rat liver results in the incorporation of atmospheric oxygen in the 5-exo-hydroxylation product. Cumene [ 02]hydroperoxide will transfer its peripheral oxygen atom to a variety of compounds which serve as substrates for mammalian cytochrome P-450. As expected, 02 served as the oxygen source for the bacterial cytochrome P-450 catalyzed epoxidation of 5,6-dehydrocamphor.N-Hydroxy-methylcarbazole, formed by the cytochrome P-450 catalyzed oxidation of N-raethylcarbazole, incorporates 0 exclusively from dioxygen. Under anaerobic conditions cytochrome P-450 may catalyze the intramolecular transfer of oxygen present in tertiary amine N-oxides. Mechanistic studies on S-dealkylation and S-oxidation reactions also have used tracer methods. ... [Pg.275]

See other pages where Amines oxygen atom transfer from hydroperoxides is mentioned: [Pg.72]    [Pg.73]    [Pg.72]    [Pg.73]    [Pg.1302]    [Pg.1302]    [Pg.1]    [Pg.904]    [Pg.40]    [Pg.85]    [Pg.197]   
See also in sourсe #XX -- [ Pg.67 , Pg.68 , Pg.69 ]



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From aminals

From amines

From oxygenates

Hydroperoxides from

Hydroperoxides oxygen atom transfer

Hydroperoxides transfer from

Oxygen amines

Oxygen atom

Oxygen atom transfer

Oxygen atom transfer amines

Oxygen atom transference

Oxygen atomic

Oxygen hydroperoxide

Oxygen transferate

Transfer from

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