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Aluminium sulphinate

Mas] Maslenkov, S.B., Molotilov, V, Micro X-Ray Diffiaction Analysis of Fe-Al-C Alloys , Fiz. Metall Metalloved., 14, 633-635 (1962) (Experimental, Meehan. Prop., 12) [1963Mor] Mori, T., Fujimura, K., Kanoshima, H., Effects of Aluminium, Sulphin and Vanadium on the Solubility of Graphite in Liquid Iron , Mem. Fac. Eng. Kyoto Imp. Univ., 25, 83-105 (1963) (Experimental, 22)... [Pg.50]

A more detailed examination of the reduction of bicyclo[2,2,l]heptane sultones [e.g. (185)] with lithium aluminium hydride reveals the formation of the corresponding sulphinates, hydroxy-mercaptans, and sulphur-free alcohols progressively, with... [Pg.37]

Reactions.—A variety of interesting and useful syntheses have been published involving the reaction of dimsyl anion [MeS(0)CHa ] with esters and lactones,with disulphides, with chlorosilanes, with sulphinate esters, with organoboranes, and with stilbenes. Simple and functionalized a-sulphinyl carbanions can be condensed with carbonyl compounds or alkylated, often in a stereocontrolled manner, as in a nicely conceived synthesis of biotin. Considerable attention has been given to methods for the removal of the sulphoxide function following carbon-carbon bond formation. Among the methods used are reduction by aluminium amalgam (with j3-keto-sulphoxides), reduction with Raney nickel, pyrolytic elimination of sulphenic acid, elimination of sulphur dioxide from sultines, e.g. (64), and sulphoxide-... [Pg.97]


See other pages where Aluminium sulphinate is mentioned: [Pg.482]    [Pg.482]    [Pg.279]    [Pg.279]    [Pg.383]    [Pg.450]    [Pg.14]    [Pg.301]    [Pg.67]    [Pg.223]    [Pg.100]   
See also in sourсe #XX -- [ Pg.482 ]




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