Allylic trifluoroacetoxylation

Allylic trifluoroacetoxylation. This salt is more reactive than mercury(Il) acetate for allylic hydroxylation. Thus cholesterol esters are converted, after hydrolysis, into A -3/3,6 -dihydroxy steroids, even at 0°. Yields are about 50%. A -3 -Aminosteroids are converted into mixtures of A -3/3-amino-4/3-hydroxy-... 

Allylic alcohols, 1, 17, 28-29, 30-31, 85-86, 182, 261, 318, 335, 338, 425, 444, 588, 602-603, 604, 664 AUyUc amines, 604-605 Allyhc chlorides, 598, 645 Aiiylic dibromides, 418 AUylic ethers, 269 Allylic halides, 327, 329 Allyhc hydroperoxides, 287 Allylic phosphine oxides, 340 Allylic rearrangement, 11-12 Allylic trifluoroacetoxylation, 360-361 Allylidenetriphenylphosphorane, 14-15 a-Allylpalladium chloride complexes, 45-47... 

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