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Allylic C-O bond cleavage

The other factor to enhance the ease of the allylic C-O bond cleavage is the interaction of the transition metal with the C=C bond in the allylic entity. The... [Pg.163]

In a somewhat different sequence involving allylic C—O bond cleavage, regiodivergent RRM has been observed in the reaction of dihydrofuran (R,S)-111 with ethylmagnesium chloride and a chiral zirconium catalyst 112 (Scheme 6.24) [44]. The formation of 113 and 114 occurs via carbometaUation of the alkene followed... [Pg.241]


See other pages where Allylic C-O bond cleavage is mentioned: [Pg.164]    [Pg.189]   
See also in sourсe #XX -- [ Pg.557 , Pg.558 ]




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Allyl bonded

Allyl cleavage

Allylation C=O bond

Allylic C-0 bond cleavage

Allylic bond cleavage

Allylic cleavage

C cleavage

C-0 bond cleavage

C-Allylation

C=O bonds

O allyl

O-Allylation

O-bond cleavage

O-cleavage

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