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Allylcyclohexadienones

The most commonly encountered examples of this type arc the 4-allylcyclohexadienones and their derivatives, such as (88), which undergo room temperature Cope rearrangement, followed by aromatiza-tion, in the presence of acid7 - It is interesting that the 3,3-Cope rearrangement competes with 1,2-migration (acid-catalyzed dienone-phenol rearrangement). [Pg.801]


See also in sourсe #XX -- [ Pg.48 ]




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Cope rearrangement of allylcyclohexadienone

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