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Allylation of gem-diacetates

Yadav JS, Reddy BVS, Madhuri C, Sabitha G (2001) Indium(III) chloride catalyzed allylation of gem-diacetates a facile synthesis of homoallyl acetates. Chem Lett 18... [Pg.63]

Indium(III) chloride catalyzes the allylation of gem-diacetates with allyltrimethylsi-lane to afford the corresponding homoallylic acetates (Scheme 8.131) [174]. Gly-cals react with silyl nucleophiles, e.g. allyltrimethylsilane, cyanotrirnethylsilane, and azidotrimethylsilane, in the presence of a catalytic amount of InBr, to give the corresponding 2,3-unsaturated allyl-, cyano-, and azidoglycosides, respectively (Scheme 8.132) [175]. [Pg.376]

See other pages where Allylation of gem-diacetates is mentioned: [Pg.247]    [Pg.228]    [Pg.389]   
See also in sourсe #XX -- [ Pg.389 ]



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GEM

Gem-diacetate

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