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Allylation of Carbonyls Methodology and Stereochemistry

The Brown asymmetric crotylation is a highly regioselective and stereospecific reaction. Many organoboranes are now commercial available. Reviews (a) Denmark, S. E. Alrnstcad, N. G. In Modem Carbonyl Chemistry, Otera, J, Ed. Wiley-VCH Weinheim, 2000 Chapter 10 Allylation of Carbonyls Methodology and Stereochemistry,... [Pg.139]

The Sakurai allylation works with a variety of Lewis acid catalysts such as TiCU, AICI3, SnCl4, LtAICL, in addition to BF3 OEt. Reviews (a) Denmark, S. E. Almstead, N. G. In Modem Carbonyl Chemistry Otera, J., Ed. Wiley-VCH Weinheim, 2000 Chapter 10 Allylation of Carbonyls Methodology and Stereochemistry, pp. 299-402. (b) Chemler, S. R. Roush, W. R. In Modern Carbonyl Chemistry, Otera, J., Ed. Wiley-VCH Weinheim, 2000 Chapter 11 Recent Applications of the Allylation Reaction to the Synthesis of Natural Products, pp. 403-490. (c) Demnark, S. E. Fu, J. Chem. Rev. 2003,103, 2763-2793. [Pg.160]


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Allylic stereochemistry

And stereochemistry

Carbonyl allylation

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