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Alkyny lation

In 2002, Braga el al. employed a chiral C2-symmetric oxazolidine disulfide as a ligand for the enantioselective synthesis of propargylic alcohols by direct addition of alkynes to aldehydes (Scheme 3.64). Good yields but moderate enantioselectivities (<58% ee) were obtained for the enantioselective alkyny-lation of aldehydes in the presence of ZnEt2. [Pg.144]

Recent reviews on Pd-catalyzed alkyny-lation (a) E. Negishi, L. Anastasia,... [Pg.82]

Alkynyl(phenyl)iodonium salts have found synthetic application for the preparation of various substituted alkynes by the reaction with appropriate nucleophiles, such as enolate anions [980,981], selenide and telluride anions [982-984], dialkylphosphonate anions [985], benzotriazolate anion [986], imidazolate anion [987], N-functionalized amide anions [988-990] and transition metal complexes [991-993]. Scheme 3.291 shows several representative reactions the preparation of Ai-alkynyl carbamates 733 by alkynylation of carbamates 732 using alkynyliodonium triflates 731 [989], synthesis of ynamides 735 by the alkyny-lation/desilylation of tosylanilides 734 using trimethylsilylethynyl(phenyl)iodonium triflate [990] and the preparation of Ir(III) a-acetylide complex 737 by the alkynylation of Vaska s complex 736 [991]. [Pg.271]


See other pages where Alkyny lation is mentioned: [Pg.402]    [Pg.198]    [Pg.748]    [Pg.139]    [Pg.697]    [Pg.748]    [Pg.402]    [Pg.198]    [Pg.748]    [Pg.139]    [Pg.697]    [Pg.748]   
See also in sourсe #XX -- [ Pg.171 ]




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