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Alkynes acyloxymercuration

The acyloxymercuration of alkynes has been reported to produce a wide variety of products. Terminal alkynes afford either dialkynylmercurials516,517 or polymercurated products whose structures have not been well established (equation 290). Internal alkynes usually afford vinylic mercurials in which the mercury(II) salt has added in an anti fashion (equation 291 ).518-520 Only sodium borohydride has been used to demercurate a few of these mercurials.520... [Pg.315]

See also in sourсe #XX -- [ Pg.315 ]

See also in sourсe #XX -- [ Pg.4 , Pg.315 ]

See also in sourсe #XX -- [ Pg.4 , Pg.315 ]



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Acyloxymercuration

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