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Alkyl halides Schlenk equilibrium

Schlenk equilibrium concept sot forth above, the magnesium halide component of tertiary alkyl Grignard reagents causes halohydria formation faster than the diaJkylmagnesium component can add. Spocial conditions have, howover. been found, which permit addition of (erf-butylmagnesium chloride to ethylene oxide (Eq. 818), giving a modest yield of the desired primary alcohol.1484 1101... [Pg.475]

Equilibrium constants estimated for the Schlenk equilibria of ethylmagnesium bromide (iodide) and phenylmagnesium bromide (iodide) in diethyl ether are shown in Table 3. Equilibria lie strongly to the side of the alkyl- and arylmagnesium halides for both substituents [27]. [Pg.278]

See other pages where Alkyl halides Schlenk equilibrium is mentioned: [Pg.339]    [Pg.108]    [Pg.387]    [Pg.292]    [Pg.302]    [Pg.475]    [Pg.292]    [Pg.301]    [Pg.582]    [Pg.63]    [Pg.67]    [Pg.384]    [Pg.1274]    [Pg.250]    [Pg.415]    [Pg.745]    [Pg.372]    [Pg.57]    [Pg.419]    [Pg.359]    [Pg.74]   
See also in sourсe #XX -- [ Pg.108 , Pg.134 ]



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