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Alkyl halide-titanocene system

Carbonyl Olefination Utilizing an Alkyl Halide-Titanocene(ll) System... [Pg.176]

An alkyl halide-titanocene(II) system offers an operationally straightfortvard method for carbonyl olefination, tvhich is believed to be mechanistically analogous... [Pg.176]

Scheme 4.39. Plausible reaction pathway for olefination utilizing an alkyl halide-titanocene(ll) system. Scheme 4.39. Plausible reaction pathway for olefination utilizing an alkyl halide-titanocene(ll) system.
Several organometallic reagents have surfaced in recent years for the reduction of the carbon-halogen bond. A titanocene dichloride-magnesium system reduces alkyl halides to alkanes under mild conditions and in good yield (equation 52) . New reagents based on 9-borabicyclo[3.3.1]nonane ( 9-BBN ) ate complexes have been used for the efficient reduction of tertiary halides (equation 53) ... [Pg.572]

See other pages where Alkyl halide-titanocene system is mentioned: [Pg.797]    [Pg.81]    [Pg.177]    [Pg.564]    [Pg.181]   
See also in sourсe #XX -- [ Pg.176 ]



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