Alkanenitrile

Aminotrimethanephosphonic acid is formed from formamide, acetamide, urea, or alkanenitriles with phosphorous acid [296]. By reaction of monoalkyl phosphite or P406 with glacial acetic acid or the corresponding anhydride ethane-1 -hydroxy-1,1-diphosphonic acid is formed after hydrolysis [297,298]. P406 can be obtained from P4 and 02 in a high yield of 85-90% [299]. 

Alkanenitriles readily gave 1 1 and 2 1 adducts with MF5 137 103 the 2 1 adducts are ioni and should be formulated as [MF4L4][MF6], while the 1 1 adducts are neutral [MF5L]. Th< penta-chlorides, -bromides and -iodides afforded the monomolecular [MX5(RCN)] (Table 5).13... 

Ni(PCy3)2 reacts in toluene with alkanenitriles R(Ph)CHCN (R = H, Me) according to equation (36).201... 

The observation that the CH2 group contributes a constant amount to the property of a compound has been made for many properties and also applies to Vm- Van Krevelen [11] has listed the CH2 contribution to VM from 12 different GCMs ranging between 16.1 and 16.6 cm3 mol-1. Jannelli et al. [12] have reported a simple linear relationship between Vm at 25°C and NCh2 for n-alkanenitriles (C2-Cg). Further, they review analogous relationships for alkanes, alcohols, diols, ethers, and amines. 

Janelli, L., M. Pansini, and R. Jalenti, Partial Molar Volumes of C2-C6 n-Alkanenitriles and Octanenitrile in Dilute Aqueous Solutions at 298.16 K. J. Chem. Eng. Data, 1984 29, 266-269. 

Method of Wakita, Yoshlmoto, Miyamoto, and Watanabe The Wakita et al. method [46] has been derived with a set of 307 liquid compounds, including alkanes, alkenes, alkynes, halogenated alkanes, alkanols, oxoalkanes, alkanones, alkyl alkanoates, alkanethiols, alkanenitriles, nitroalkanes, and substituted benzenes, naphthalenes, and biphenyles. The model equation is... 

Polarizability-Kow Relationships Molar polarizabilities can be derived from molecular orbital (MO) calculations by the complete neglect of differential overlap (CNDO) method [42]. The following correlation has been found for polar compounds that contain either hydrogen-bond-accepting or hydrogen-bond-donating groups (alkanols, alkanones, dialkyl ethers, alkanenitriles) ... 

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