Alkane diazotates

AtoxyaUumes The reaction of alkane diazotates (probably syn) with triethyl-oxoaium fluoroborate in CHjQz suspensions gives azoxyalkanes in 50-60% yield ... 

Alternatively, azoxyalkanes can be prepared by the reaction of alkane diazotates with alkyl halides (preferably iodides) in hexamethylphosphoric triamide. 

Alkaneboronic acids, 25 Alkane diazotates, 528 Alkeneboronic adds, 70... 

We begin the discussion on deaminations of open-chain amines with the only case in which the rate-limiting step is the formation of the alkanediazonium ion. This brings us to the evaluation of compounds in which the amino group is attached to C(l) of an -alkane. Two relatively recent investigations of Fishbein s and Kirmse s groups (Hovinen and Fishbein, 1992 Brosch and Kirmse, 1991), using diazotization kinetics of methylamine and the deamination products of two stereochemically pure 1-amino [1- H] alkanes, respectively, elucidated clearly fundamental problems of... 

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