Alkane bpmen

A linear tetradentate ligand, bpmen [N,N -dimethyl-N,N -bis(2-pyridylmethyl)-l,2-diaminoethane] was reported to allow stereospecific alkane hydroxylation [36, 40], The same holds true for the [Fen(TPA)(CH3CN)2]2+ [TPA = tris(2-pyridylmethyl) amine] catalyst family (Figure 3.3) [35],... 

Excellent oxidant-to-product conversion (70 % based on H2O2 in 30 min) and highly stereospecific alkane hydroxylation was observed in the oxidation reaction catalyzed by [Fe(bpmen)(CH3CN)2](C104)2 45). The oxidation of cis-... 

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