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Alkali metal-arsenic clusters

Alkali Metal-Phosphorus and Alkali Metal-Arsenic Clusters I 403... [Pg.403]

Metal-Phosphorus and Alkali Metal—Arsenic Clusters I 409... [Pg.409]

A series of alkali metal and alkaline earth metal-arsenic clusters formulated as M[c-Ass] (M = Li, Na, K, Rb, Cs) andM [c-Ass]+(M = Be, Mg, Ca, Sr, Ba) were investigated by Xu and Jin [173] using DFT methods. All M[c-Assj andM [c-Ass]" clusters adopt a pentagonal pyramidal structure with Csv symmetry, its basal plane involving the planar pentagonal [c-Ass] anion. From molecular orbital and NICS analysis, it was established that each of these species had three delocalized n MOs that satisfied the 4h - - 2 electron counting rule and therefore exhibit n-aromatic character. [Pg.261]

See other pages where Alkali metal-arsenic clusters is mentioned: [Pg.197]    [Pg.257]    [Pg.257]    [Pg.39]    [Pg.5843]    [Pg.76]    [Pg.18]    [Pg.391]   
See also in sourсe #XX -- [ Pg.403 ]



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Alkali clusters

Arsenic clusters

Clusters alkali metal

Metallic arsenic

Metals arsenic

Phosphorus alkali metal-arsenic clusters

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