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Aligned porous sugar acetate

Recently, an entirely new approach to prepare porous materials was developed by templating the structure of solid CO2 by directional freezing [36]. In this process, a liquid CO2 solution was frozen in liquid nitrogen uni-directionaUy. The solid CO2 was subsequently removed by direct sublimation to yield a porous, solvent-free structure with no additional purification steps (Fig. 1). Other C02-soluble actives could be incorporated into the porous structure uniformly. This was demonstrated by dispersing oil red uniformly in the aligned porous sugar acetates [36]. This method differs fundamentally from the other C02-based techniques [ 14-29], and offers the unique advantage... [Pg.385]

Fig. 1. Aligned porous sugar acetate produced by directional freezing of liquid CO2 solution. The red arrow represents the approximate direction of freezing. Reproduced with permission copyright 2005 American Chemical Society [36],... Fig. 1. Aligned porous sugar acetate produced by directional freezing of liquid CO2 solution. The red arrow represents the approximate direction of freezing. Reproduced with permission copyright 2005 American Chemical Society [36],...

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