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Aldehydes safety-catch linkers

A novel use of the Pummerer rearrangement is as a method for cleavage of sulfide safety-catch linkers. The sulfide safety-catch linker is oxidised to the sulfoxide, Pummerer rearrangement then takes place, followed by cleavage to give the desired alcohols and aldehydes. [Pg.349]


See other pages where Aldehydes safety-catch linkers is mentioned: [Pg.48]    [Pg.61]    [Pg.428]    [Pg.443]    [Pg.445]    [Pg.298]    [Pg.38]    [Pg.95]    [Pg.55]    [Pg.27]    [Pg.579]   
See also in sourсe #XX -- [ Pg.445 ]




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