Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Aldehydes acyllithium addition

R = n-.s-.f-Bu R = Alkyl, Aryl Scheme 13 Acyllithium addition to aldehydes... [Pg.217]

Murai and coworkers reported on operationally simple aldol reactions with lithium enolates generated from carbonylation of silylmethyl lithium species [57]. Upon 1,2-silicon shift, a-silyl acyllithium species can be stereo-selectively converted to (E) lithium enolates that undergo addition to aldehydes to give /3-hydroxy acylsilanes (Scheme 14). [Pg.223]


See other pages where Aldehydes acyllithium addition is mentioned: [Pg.223]    [Pg.223]    [Pg.217]    [Pg.142]    [Pg.193]    [Pg.207]    [Pg.216]    [Pg.89]   
See also in sourсe #XX -- [ Pg.217 ]

See also in sourсe #XX -- [ Pg.217 ]




SEARCH



Acyllithium

Acyllithiums

Addition aldehydes

© 2024 chempedia.info