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Alcohols by dimethyl sulfoxide

Formation of methylthiomethyl ethers is often observed in oxidation of alcohols by dimethyl sulfoxide-acetic anhydride. Suggest a mechanism that would account for the formation of these by-products. [Pg.404]

Note Pfitzner-Moffatt reaction represents oxidation of primaiy and secondary alcohols by dimethyl sulfoxide (DMSO) activated with carbodiimides, usually dicyclohexylcarbodiimide (DCC). Intermediary alkoxysulfonium ylides rearrange to aldehydes or ketones. This reaction yields urea as a by-product that is difficult to... [Pg.207]

See other pages where Alcohols by dimethyl sulfoxide is mentioned: [Pg.652]    [Pg.492]   
See also in sourсe #XX -- [ Pg.356 , Pg.357 ]

See also in sourсe #XX -- [ Pg.487 , Pg.488 ]



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Alcohols dimethyl sulfoxide

Sulfoxides dimethyl

Sulfoxides dimethyl sulfoxide

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