Akabori

Snyder and Smith prepared diethyl acetamidomalonate in 40% yield by reduction of diethyl isonitrosomalonate in ethanol over palladium on charcoal followed by direct acetylation of diethyl aminomalonate in the filtrate with acetic anhydride. Ghosh and Dutta used zinc dust instead of palladium. A modification using Raney nickel is described by Akabori et al. Shaw and Nolan reported a 98% yield by conversion of diethyl oximino-malonate-sodium acetate complex. 

Akabori and Saito obtained 6-methoxy-3-indolylacetonitrile (231) from 6-methoxyindole and chloroacetonitrile by the Grignard reaction/ and Wieland et al. prepared 5 methoxy-3-indolylaceto-... 

Akabori, K. Fujimoto, H. A Method for Measuring Cell Membrane Thickness of Polyurethane Foam, International Progress in -Urethanes. 1980, 2, 1-61. 

The simplest amino acid, glycine, is almost always the one formed in highest yield in prebiotic syntheses. Thus, the first polycondensation experiments were carried out with glycine. Akabori (1955) and Hanabusa and Akabori (1959) reacted aminoace-tonitrile with kaolin at 403 108 K. The starting material is readily formed as follows ... 

The benzoin condensation of benzaldehyde in the presence of potassium cyanide has been studied by Akabori et al. (1976). Under liquid-liquid... 

Akabori and Yoshii (1978) used sodium hydride to generate the carbanions of cr-chloro esters [142], which reacted with cg -unsaturated esters to... 

In the presence of 8 molar equivalents of NaSCN c Akabori and Yoshii, 1978... 

S Akabori, S Sakakibara, Y Shimonishi. Protection of amide nitrogen for peptide synthesis. A novel synthesis of peptides containing C-terminal glutamine, (xanthenyl) Bull Chem Soc Jpn 34, 739, 1961. 

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