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Aggregation reactions cluster synthesis

When the irradiation of metal ion solutions is performed in the presence of the ligands CO or PPhs, metal reduction, ligandation, and aggregation reactions compete, leading to reduced metal complexes and then to stable molecular clusters, such as Chini clusters Pt3(CO)6] with m = 3-10 (i.e., 9-30 Pt atoms) [97], or other metal clusters [98]. The synthesis is selective and m is controlled by adjusting the dose m decreases at high doses). The mechanism of the reduction has been determined recently by pulse radiolysis [99]. Molecular clusters [Pt3(CO)6]5 have been observed by STM [100]. [Pg.592]


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See also in sourсe #XX -- [ Pg.171 ]

See also in sourсe #XX -- [ Pg.171 ]




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