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Addition Reactions to Double Bonds

The stoichiometric equivalents of halogen fluorides, i.e. chlorine monofluoride, bromine monofluoride and iodine monofluoride, have found a wide application in addition reactions to double bonds. The equivalents are obtained by reacting A -haloamides or free halogens in combination with hydrogen fluoride or its salts as the source of fluoride ions. The reactions proceed under mild conditions at — 80 to 20 "C in anhydrous hydrofluoric acid or diethyl ether, tetrahydro-furan, dichloromethane or chloroform mainly by electrophilic addition with Markovnikov-type regioselectivity (anti addition).26-28... [Pg.238]

Because of the lack of quantitative data we shall not comment further op the structural aspects of the abstraction reactions of CH2 or on their addition reactions to double bonds.20... [Pg.19]

This section deals with C-C bond forming asymmetric transition metal catalyzed addition reactions to double bonds. The material is divided into hydrocarboration, dicarboration and heterocarboration reactions. [Pg.286]

OTHER ADDITION REACTIONS TO DOUBLE BONDS 11.6.1 Ethylene Derivatives... [Pg.528]

Structure elucidation of 5-lactaranolides other relevant chemical transformations involved the conversion of the lactone into the furan ring and addition reactions to double bonds (hydrogenation, hydroboration, epo-xidation, osmylation). A brief account of these reactions will be included in the chapter on chemical conversions of Lactarius sesquiterpenes. [Pg.102]

VI. Other Addition Reactions to Double Bonds Vn. Oxidation Reactions of Polymers Vin. Functionalization of Polymers IX. Miscellaneous Chemical Reactions of Polymers X. Block and Graft Copolymerization References... [Pg.497]

See other pages where Addition Reactions to Double Bonds is mentioned: [Pg.248]    [Pg.129]    [Pg.536]    [Pg.556]    [Pg.557]    [Pg.559]    [Pg.51]    [Pg.6844]    [Pg.502]    [Pg.538]    [Pg.558]    [Pg.559]    [Pg.591]    [Pg.93]    [Pg.168]   


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Addition reaction double

Addition reactions bonds

Addition reactions of double bonds, adjacent to carboxylate

Additions to-double bonds

Double bond, addition

Double bonds, reactions

Other Addition Reactions to Double Bonds

Radical Addition Reactions to Double Bonds

Reaction double

Reactions of Silenes Additions to the Double Bond

Reactions to double bonds

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