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Addition of Anodically Generated Radicals to Double Bonds

The Kolbe electrolysis is a convenient source for alkyl radicals R (Eq. (94) ). If conducted in the presence of olefins, e.g., butadiene, isoprene, cyclohexadiene, or styrene, the intermediate radicals R add to the double bond to form adducts 49, which dimerize to additive dimers JO or couple with R to disubstituted monomers 51 (Eq. (114) ) 257 26°). [Pg.78]

Some synthetic applications of this reaction are summarized in Table 7. [Pg.78]

Potassium ethyl oxalate (MeOH) Butadiene Diethyl 3,7-decadiene-l,10-dicarboxylate7 7 (40%)  [Pg.78]

Potassium acetate (acetic acid, MeOH) Butadiene trans-3-Hexene (11-26%), 1-pentene 257,258) 3-methyl-1-pentene, CjQ-dienes (12-58%), 3,7-decadiene, 3-ethyl-l,5-octadiene  [Pg.78]

Trifluoroacetate, trifluoroacetic acid, MeOH Butadiene 1,1,1,10,10,10-Hexafluoro-3,7 -deca-diene, other products 257) [Pg.78]


See other pages where Addition of Anodically Generated Radicals to Double Bonds is mentioned: [Pg.77]    [Pg.78]   


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Addition bonds, radical

Addition of radicals

Additions to-double bonds

Anodic addition

Anodic bonding

Double bond, addition

Generating Radicals

Of double bonds

Radical generators

Radicals addition to double bonds

Radicals bonding

Radicals generation

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