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Addition at Double Bonds via Organoborane Intermediates

Some of the most synthetically useful addition reactions of alkynes are with organometallic reagents, and these reactions, which can lead to carbon-carbon bond formation, are discussed in Chapter 8. [Pg.337]

Addition at Double Bonds via Organoborane Intermediates 4.5.1. Hydroboradon [Pg.337]

Borane, BH3, having only six valence electrons on boron, is an avid electron pair acceptor. Pure borane exists as a dimer in which two hydrogens bridge the borons. [Pg.337]

In aprotic solvents that can act as electron pair donors such as ethers, tertiary amines, and sulfides, borane forms Lewis acid-base adducts. [Pg.337]


SECTION 4.9. ADDITION AT DOUBLE BONDS VIA ORGANOBORANE INTERMEDIATES... [Pg.227]


See other pages where Addition at Double Bonds via Organoborane Intermediates is mentioned: [Pg.337]    [Pg.339]    [Pg.341]    [Pg.343]    [Pg.345]    [Pg.347]    [Pg.351]    [Pg.226]   


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