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Adamantanoid architectures

For instance, adamantanoid architectures are formed on the self-assembly of tetradentate XB donors with tetradentate XB acceptors, both the complementary tectons alternating at the nodes of the network (this is the case in the complex CBr4/Et4N+Cl and its bromide and iodide analogues [192], in the complex tetrakis(4-pyridyl)pentaerythritol/tetrakis(4-iodiotetralluorophenyl)pentaerythritol [195], and in other systems [197]). [Pg.137]

Fig. 14 Different adamantanoid architectures formed on self-assembly of A a self-complementary tetradentate module B a tetradentate XB acceptor and a bidentate XB donor C a tetradentate XB acceptor and a tetradentate XB donor... Fig. 14 Different adamantanoid architectures formed on self-assembly of A a self-complementary tetradentate module B a tetradentate XB acceptor and a bidentate XB donor C a tetradentate XB acceptor and a tetradentate XB donor...
Adamantanoid architectures are formed also on the self-assembly of tetradentate XB acceptors, that sit at the nodes, with bidentate XB donors, that work as nodes spacers (e.g. in the complex l,4-diiodooctafluorobutane/tetrakis(4-pyridyl)pentaerythritol [195]). [Pg.138]

An example of 3D architecture is the adamantanoid network that is formed after various self-assembly protocols. This network is in fact present in the... [Pg.136]

Figure 2.2. Proposed architecture for mesostructured metal germanium sulphides. Adamantanoid clusters [Ge4S10]4 link upon addition of a metal salt to form a supra-molecular mesostructured material where surfactant molecules charge balance the negative charge on the framework. Reproduced with permission from [38]. Figure 2.2. Proposed architecture for mesostructured metal germanium sulphides. Adamantanoid clusters [Ge4S10]4 link upon addition of a metal salt to form a supra-molecular mesostructured material where surfactant molecules charge balance the negative charge on the framework. Reproduced with permission from [38].

See also in sourсe #XX -- [ Pg.127 ]

See also in sourсe #XX -- [ Pg.127 ]




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