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Acyclic pentadienyl ligands complexes

Over the past 20 years, there has been a growing interest in the use of acyclic (or open) ( 7 -pentadienyl)iron cations 1 (Scheme 1) as synthetic tools for G-C bond formation. Complexation of Fe(CO)3 to a diene distinguishes between two enantiotopic faces of the ligand and directs diastereoselective bond formation at unsaturated centers adjacent to the coordinated diene. In addition, the electron-donor ability of the carbonyliron group allows for the generation of cationic centers adjacent to the coordinated diene. ... [Pg.153]

See other pages where Acyclic pentadienyl ligands complexes is mentioned: [Pg.13]    [Pg.5207]    [Pg.5206]    [Pg.252]    [Pg.125]    [Pg.126]    [Pg.149]    [Pg.2]    [Pg.2084]    [Pg.3589]    [Pg.2083]    [Pg.3588]    [Pg.900]    [Pg.900]   
See also in sourсe #XX -- [ Pg.128 ]



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